Firefighter exposures to organic and inorganic gas emissions in emergency residential and industrial fires

Abstract

The gas emissions generated from fires could cause mortalities and diseases in firefighters. Gas emissions from fire contain a mixture of a wide range of organic and inorganic gases, depending on several elements that are not currently known. In this study, firefighters were equipped with portable gas detectors to measure selected organic and inorganic gases in 26 emergency fire incidents. The fire incidents were categorized as industrial or residential based on their source. The exposure of firefighters to volatile organic compounds (VOCs) in residential fires was double that in industrial fires. This is probably due to the contents of the houses, as more VOCs are released from textiles and furniture. The concentration of toluene, which is widely used in cosmetics and paints in housing, was fifteen-fold higher in residential fires than industrial fires. The exposure of firefighters to inorganic gases was much higher in industrial fires than residential fires. The concentration of hydrogen chloride, which is generated from the combustion of chlorinated plastics, such as industrial pipes and cables, in industrial fires was 18-fold higher than that in residential fires. Additionally, in this study, we found that the concentration of VOCs that poses cancer and non-cancer health risk to firefighters increases in residential fire incidents to almost three times that in industrial fire incidents. Hydrogen sulfide and sulfur dioxide concentrations were higher in industrial fire incidents than in residential fire incidents. The level of hydrogen sulfide and sulfur dioxide were 19-fold and 8-fold higher, respectively, in industrial fire incidents than in residential fire incidents. This study reveals that gas emissions vary widely between industrial and residential fires.

Keywords: Fire exposure; Firefighters; Industrial fires; PVC; Residential fires; VOCs.