Structure and properties of oxycellulose fabric crosslinked with soy protein

Abstract

Cotton is an important renewable biopolymer with extensive applications in various fields including textiles. In the current study a soy protein (SP) crosslinked cotton fabric (SPCCF) was prepared through the reaction of carboxyl cotton fabric with soy protein without using crosslinking agents. FTIR analysis of SPCCF samples indicated that carboxyl groups in oxycellulose fabric have reacted with amino groups of SP to give the corresponding C-N bond, that was also reconfirmed by XPS spectra and TGA/DTG analyses of the grafted fabrics. The resulting SPCCF fabrics acquired under the optimized conditions exhibited the improved tensile strength and capillary effect as compared to the oxidized cotton fabric. The ungrafted and grafted fabrics were further evaluated for dyeing property, as a result, the SPCCF fabrics showed markedly improved colour strength when dyed with acid dyes. The fastness properties of dyeability for the dyed SPCCF fabrics were also good compared with that of ungrafted fabrics by dyeing. Shikonin as a kind of Chinese medicine was found to immobilize on the SPCCF fabric through treatment with shikonin aqueous solution, such fabric displayed effective antibacterial activities against both gram-positive and gram-negative bacteria with durability of 30 washes. These results suggest that the SPCCF can be suitable for medical protective textiles by immobilizing drugs.

Keywords: Antibacterial activity; Dyeing; Oxycellulose; SP-crosslinked oxycellulose; Shikonin.