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. 2021 Feb 23;50(7):2350-2353.
doi: 10.1039/d0dt04149a.

Elucidating the paramagnetic interactions of an inorganic-organic hybrid radical-functionalized Mn-Anderson cluster

Chang-Gen Lin  1 , Marie Hutin  2 , Christoph Busche  2 , Nicola L Bell  2 , De-Liang Long  2 , Leroy Cronin  2
Affiliations
Free article

Elucidating the paramagnetic interactions of an inorganic-organic hybrid radical-functionalized Mn-Anderson cluster

Chang-Gen Lin et al. Dalton Trans. .
Free article

Abstract

A family of six polyoxometalate-based magnetic compounds were synthesized by anchoring N-oxide type TEMPO radicals onto an Anderson type polyoxometalate cluster. The complexes were structurally characterised by single crystal X-ray diffraction and the intramolecular paramagnetic interactions between TEMPO radicals and Mn ions of the resulting hybrids were investigated in detail by electron paramagnetic resonance and the Evans NMR method.

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