Pore wettability for enhanced oil recovery, contaminant adsorption and oil/water separation: A review

Abstract

Wettability, a fundamental property of porous surface, occupies a pivotal position in the fields of enhanced oil recovery, organic contaminant adsorption and oil/water separation. In this review, wettability and the related applications are systematically expounded from the perspectives of hydrophilicity, hydrophobicity and super-wettability. Four common measurement methods are generalized and categorized into contact angle method and ratio method, and influencing factors (temperature, the type and layer charge of matrix, the species and structure of modifier) as well as their corresponding altering methods (inorganic, organic and thermal modification etc.) of wettability are overviewed. Different roles of wettability alteration in enhanced oil recovery, organic contaminant adsorption as well as oil/water separation are summarized. Among these applications, firstly, the hydrophilic alteration plays a key role in recovery of the oil production process; secondly, hydrophobic circumstance of surface drives the organic pollutant adsorption more effectually; finally, super-wetting property of matrix ensures the high-efficient separation of oil from water. This review also identifies importance, challenges and future prospects of wettability alteration, and as a result, furnishes the essential guidance for selection and design inspiration of the wettability modification, and supports the further development of pore wettability application.

Keywords: Adsorption; Enhanced oil recovery; Oil/water separation; Organic contaminant; Wettability.