Twisted Molecular Nanoribbons with up to 53 Linearly-Fused Rings

Abstract

The synthesis of three molecular nanoribbons with a twisted aromatic framework is described. The largest one shows a 53 linearly fused rings backbone (12.9 nm) and 322 conjugated atoms in its aromatic core (C₂₉₆N₂₄S₂). This new family of nanoribbons shows extremely high molar absorptivities, reaching 986 100 M^-1 cm^-1, and red-emitting properties.