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. 2021 May 27;18(11):5733.
doi: 10.3390/ijerph18115733.

Spatial Analysis of Groundwater Hydrochemistry through Integrated Multivariate Analysis: A Case Study in the Urbanized Langat Basin, Malaysia

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Spatial Analysis of Groundwater Hydrochemistry through Integrated Multivariate Analysis: A Case Study in the Urbanized Langat Basin, Malaysia

Nur Fatihah Mohamad Zainol et al. Int J Environ Res Public Health. .

Abstract

Rapid urbanization and industrial development in the Langat Basin has disturbed the groundwater quality. The populations' reliance on groundwater sources may induce possible risks to human health such as cancer and endocrine dysfunction. This study aims to determine the groundwater quality of an urbanized basin through 24 studied hydrochemical parameters from 45 groundwater samples obtained from 15 different sampling stations by employing integrated multivariate analysis. The abundance of the major ions was in the following order: bicarbonate (HCO3-) > chloride (Cl-) > sodium (Na+) > sulphate (SO42-) > calcium (Ca2+) > potassium (K+) > magnesium (Mg2+). Heavy metal dominance was in the following order: Fe > Mn > Zn > As > Hg > Pb > Ni > Cu > Cd > Se > Sr. Classification of the groundwater facies indicated that the studied groundwater belongs to the Na-Cl with saline water type and Na-HCO3 with mix water type characteristics. The saline water type characteristics are derived from agricultural activities, while the mixed water types occur from water-rock interaction. Multivariate analysis performance suggests that industrial, agricultural, and weathering activities have contributed to groundwater contamination. The study will help in the understanding of the groundwater quality issue and serve as a reference for other basins with similar characteristics.

Keywords: groundwater assessment; groundwater quality; heavy metals; major ions; multivariate statistical analysis; weathering.

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Conflict of interest statement

The authors declare no conflict of interest.

Figures

Figure 1
Figure 1
The land use map of the Langat basin.
Figure 2
Figure 2
Piper trilinear diagram showing hydrogeochemical facies. Na-HCO3 water type (Circle I) and Na-Cl water type (circle II).
Figure 3
Figure 3
The Gibbs diagram showing the mechanism governing groundwater chemistry.
Figure 4
Figure 4
Scree plot for PCA.
Figure 5
Figure 5
Rotated component of PCA.
Figure 6
Figure 6
Classification of the sampling stations based on HCA outputs.

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