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Review
. 2021 Dec;21(12):3674-3688.
doi: 10.1002/tcr.202100133. Epub 2021 Jun 8.

Carbon-Sulfur Bond Constructions: From Transition-Metal Catalysis to Sustainable Catalysis

Pratheepkumar Annamalai  1 , Ke-Chien Liu  1 , Satpal Singh Badsara  2 , Chin-Fa Lee  1   3   4
Affiliations
Review

Carbon-Sulfur Bond Constructions: From Transition-Metal Catalysis to Sustainable Catalysis

Pratheepkumar Annamalai et al. Chem Rec. 2021 Dec.

Abstract

The recent decade evidenced a significant development in the construction of the C-S bond. The journey began with transitional-metal catalysis and reached sustainable catalysis via oxidant, photo, and electro catalyzed methods. A variety of catalytic systems have been explored for the C-S bond formation using a variety of sulfur precursors. This personal account provides an inclusive discussion of these developed methods in terms of reactivity, sustainability and productivity.

Keywords: Copper; Cross-coupling; C−H bond activation; C−S bond formation; Transition-metal.

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References

    1. For reviews on transition-metal-catalyzed C−S coupling reaction, see:
    1. C. C. Eichman, J. P. Stambuli, Molecules 2011, 16, 590-608;
    1. S. V. Ley, A. W. Thomas, Angew. Chem. 2003, 115, 5558-5607;
    1. Angew. Chem. Int. Ed. 2003, 42, 5400-5449;
    1. T. Kondo, T.-a. Mitsudo, Chem. Rev. 2000, 100, 3205-3220;

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