Multi-element signatures in solid and solution phases in a tropical mixing zone: A case study in the Cai River estuary, Vietnam

Abstract

This study provides baseline concentrations of major, trace, and rare earth elements (REEs) in the solid and solution phases of the tropical Cai River estuary under influence of multiple stresses. The application of the selected multivariate analysis tools (principal component analysis and redundancy analysis) to the enrichment factor and partitioning coefficients (K_SPM/Water and K_SPM/Sed) calculated from the bulk element contents highlighted the strongest relationships (considered as multi-element signatures) according to the efficiency of the transfer across the estuarine gradients (considered as a selective geochemical filter). Thus, most of the major and trace elements, and REEs studied mainly settle within the mixing zone due to the association with terrigenous aluminosilicate clay minerals, whereas Co, Ni, Cu, As, and Mo are transferred seaward because of their association with the most labile fraction of the fluvial particulate load (such as clays, organic colloids, and carbonates). The major and trace elements, and REEs investigated in this study are mainly introduced in the Cai River and its estuary via basement rock weathering under enhanced monsoonal precipitation, whereas Bi showed the most severe enrichment in the non-weathering distribution pattern. The fractionation of the fluvial element load within the estuarine geochemical filter is mainly controlled by the differential settling of fluvial mineral element-bearing phases along with estuarine colloid dynamics - a topic that must warrants further investigation.

Keywords: Enrichment factor; Estuarine gradients; Multi-element signatures; Nha trang bay; Partitioning patterns.