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. 1999 Jul 12;38(13-14):2052-2054.
doi: 10.1002/(SICI)1521-3773(19990712)38:13/14<2052::AID-ANIE2052>3.0.CO;2-9.

Markovnikov Hydroboration of Perfluoroalkylethylenes

Herbert C Brown  1 , Guang-Ming Chen  1 , Michael P Jennings  1 , P Veeraraghavan Ramachandran  1
Affiliations

Markovnikov Hydroboration of Perfluoroalkylethylenes

Herbert C Brown et al. Angew Chem Int Ed Engl. .

Abstract

A Markovnikov regioselectivity of 92 % or higher is achieved in the hydroboration of a series of perfluoroalkylethylenes and 2',3',4',5',6'-pentafluorostyrene with dichloro- and dibromoborane to provide the corresponding (fluoroalkyl)dihaloboranes (see reaction).

Keywords: Boranes; Fluoroalkenes; Hydroborations.

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