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. 1999 Jul 12;38(13-14):2029-2032.
doi: 10.1002/(SICI)1521-3773(19990712)38:13/14<2029::AID-ANIE2029>3.0.CO;2-A.

The First Determination of Eu-H Distances by Neutron Diffraction on the Novel Hydrides EuMg2H6 and EuMgH4

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The First Determination of Eu-H Distances by Neutron Diffraction on the Novel Hydrides EuMg2H6 and EuMgH4

Holger Kohlmann et al. Angew Chem Int Ed Engl. .

Abstract

Despite the high neutron absorption of natural europium, the crystal structures of two Eu hydrides could be solved from powder diffraction data. EuMg2D6 crystallizes in a novel AB2X6 structure type (see picture), EuMgD4 is isotypic to BaZnF4. The mean Eu-D distances are 258 and 253 pm, respectively.

Keywords: Europium; Metal hydrides; Neutron absorption; Neutron diffraction; Structure elucidation.

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