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. 2021 Jul 28;57(59):7256-7259.
doi: 10.1039/d1cc02293h. Epub 2021 Jul 1.

Stereospecific synthesis of chiral P-containing polyaromatics based on 7-membered P-rings

Réka Mokrai  1 , Anabella Mocanu, Matthew P Duffy, Thomas Vives, Elsa Caytan, Vincent Dorcet, Thierry Roisnel, László Nyulászi, Zoltán Benkő, Pierre-Antoine Bouit, Muriel Hissler
Affiliations

Stereospecific synthesis of chiral P-containing polyaromatics based on 7-membered P-rings

Réka Mokrai et al. Chem Commun (Camb). .

Abstract

We present the stereospecific synthesis of helicenoid-based phosphepines (7-membered P-rings) as well as chiral P-containing polycyclic aromatic hydrocarbons. In these systems, an axial to central chirality transfer takes place from the BINAP moiety to the P-atom. The impact of the molecular design on the structure, the (chir)optical (including circularly polarized luminescence) and redox properties are investigated.

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