Metal-organic frameworks as superior porous adsorbents for radionuclide sequestration: Current status and perspectives

Abstract

Efficient separation of hazardous radionuclides from radioactive waste remains a challenge to the global acceptance of nuclear power due to complex nature of the waste, high radiotoxicities and presence of large number of interfering elements. Sorption of radioactive elements from liquid phase, gas phase or their solid particulates on various synthetic organic, inorganic or biological sorbents is looked as one of the options for their remediation. In this context, highly porous materials, termed as metal-organic frameworks (MOFs), have shown promise for efficient capturing of various types of radioactive elements. Major advantages that have been advocated for the application of MOFs in radionuclide sorption are their excellent chemical stability, and their large surface area due to abundant functional groups, and porosity. In this review, recent developments on the application of MOFs for radionuclide sequestration are briefly discussed. Focus has been devoted to address the separation of few crucial radioactive elements such as Th, U, Tc, Re, Se, Sr and Cs from aqueous solutions, which are important for liquid radioactive waste management. Apart from these radioactive metal ions, removal of radionuclide bearing gases such as I₂, Xe, and Kr are also discussed. Aspects related to the interaction of MOFs with the radionuclides are also discussed. Finally, a perspective for comprehensive investigation of MOFs for their applications in radioactive waste management has been outlined.

Keywords: MOF; Porous solid materials; Radioactive waste; Separation.