Progress in surface-modified silicas for Cr(VI) adsorption: A review

Abstract

Various toxic chemicals are discharging to the environment due to rapid industrialization and polluting soil, water, and air causing numerous diseases including life-threatening cancer. Among these pollutants, Cr(VI) or hexavalent chromium is one of the most carcinogenic and toxic contaminants hostile to human health and other living things. Therefore, along with other contaminants, the removal of Cr(VI) efficiently is very crucial to keep our environment neat and clean. On the other hand, silica has a lot of room to modify its surfaces as it is available with various sizes, shapes, pore sizes, surface areas etc. and the surface silanol groups are susceptible to design and prepare adsorbents for Cr(VI). This review emphases on the progress in the development of different types of silica-based adsorbents by modifying the surfaces of silica and their application for the removal of Cr(VI) from wastewater. Toxicity of Cr(VI), different silica surface modification processes, and removal techniques are also highlighted. The adsorption capacities of the surface-modified silica materials with other parameters are discussed extensively to understand how to select the best condition, silica and modifiers to achieve optimum removal performance. The adsorption mechanisms of various adsorbents are also discussed. Finally, future prospects are summarized and some suggestions are given to enhance the adsorption capacities of the surface-modified silica materials.

Keywords: Adsorption; Biosorbent; Cr(VI); Environmental sustainability; Surface modification.