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. 2008 Jun 4;20(11):2105-2110.
doi: 10.1002/adma.200702605. Epub 2008 Jun 5.

Amorphous Infinite Coordination Polymer Microparticles: A New Class of Selective Hydrogen Storage Materials

You-Moon Jeon  1 , Gerasimos S Armatas  2 , Jungseok Heo  1 , Mercouri G Kanatzidis  3 , Chad A Mirkin  1
Affiliations

Amorphous Infinite Coordination Polymer Microparticles: A New Class of Selective Hydrogen Storage Materials

You-Moon Jeon et al. Adv Mater. .
No abstract available

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Figures

Figure 1.
Figure 1.
Scanning electron microscopy and dark-field optical microscopy images (inset: fluorescence microscopy images): a,b) 3, c,d) 4.
Figure 2.
Figure 2.
The crystal structure of 4: a) Ball-and-stick diagram of an asymmetric unit, b) 3D packing diagram. Hydrogen atoms and solvent molecules (7 pyridines and 1/2 water per asymmetric unit) have been omitted for clarity.
Figure 3.
Figure 3.
a) Adsorption isotherms of 3 for H2, CO2, and N2 (H2 ◆, CO2 ●, N2 ▲) (measured at 77 K for H2 and N2 and at 258 K for CO2, solid lines in isotherms are visual aids), b) isosteric heat of adsorption Qst for H2 in 3. STP: standard temperature and pressure. 1 Torr = 1.333 × 102 Pa.
Scheme 1.
Scheme 1.
Schematic representation of ICP particle synthesis. Ac: acetyl.
Scheme 2.
Scheme 2.
Selective synthesis of the metallo-salen ligand Zn(AFSL) 2, amorphous ICP particle 3, and crystalline metallomacrocycle 4. DMF: N,N-dimethyl formamide.
See this image and copyright information in PMC

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