Interfacing with Fe-N-C Sites Boosts the Formic Acid Dehydrogenation of Palladium Nanoparticles

Shan Zhong^{1

2

3}, Xinchun Yang¹, Liyu Chen⁴, Nobuko Tsumori⁵, Noboru Taguchi¹, Qiang Xu^{1

2

4

6}

Affiliations

¹ Research Institute of Electrochemical Energy, National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan.
² Graduate School of Engineering, Kobe University, Kobe, Hyogo 657-8501, Japan.
³ School of Energy and Power Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China.
⁴ AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL), National Institute of Advanced Industrial Science and Technology (AIST), and Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan.
⁵ Department of Applied Chemistry and Chemical Engineering, Toyama National College of Technology, 13 Hongo-machi, Toyama 939-8630, Japan.
⁶ Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen, Guangdong 518055, China.

PMID: 34581556
DOI: 10.1021/acsami.1c14009

Interfacing with Fe-N-C Sites Boosts the Formic Acid Dehydrogenation of Palladium Nanoparticles

Shan Zhong et al. ACS Appl Mater Interfaces. 2021.

. 2021 Oct 6;13(39):46749-46755.

doi: 10.1021/acsami.1c14009. Epub 2021 Sep 28.

Authors

Shan Zhong^{1

2

3}, Xinchun Yang¹, Liyu Chen⁴, Nobuko Tsumori⁵, Noboru Taguchi¹, Qiang Xu^{1

2

4

6}

Affiliations

¹ Research Institute of Electrochemical Energy, National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan.
² Graduate School of Engineering, Kobe University, Kobe, Hyogo 657-8501, Japan.
³ School of Energy and Power Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China.
⁴ AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory (ChEM-OIL), National Institute of Advanced Industrial Science and Technology (AIST), and Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan.
⁵ Department of Applied Chemistry and Chemical Engineering, Toyama National College of Technology, 13 Hongo-machi, Toyama 939-8630, Japan.
⁶ Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen, Guangdong 518055, China.

PMID: 34581556
DOI: 10.1021/acsami.1c14009

Abstract

Hierarchical micro-/mesoporous carbons with abundant Fe-N-C sites were prepared through one-step carbonization of a metal-organic framework (MOF) with sodium iron ethylenediaminetetraacetic acid [NaFe(III)EDTA], which can facilitate the nucleation and growth of ultrafine (∼1.4 nm) and highly dispersed palladium nanoparticles (Pd NPs). Interfacing Pd NPs with Fe-N-C sites has been demonstrated for the first time to boost the heterogeneous catalysis of hydrogen production from formic acid, affording an ultrahigh turnover frequency (TOF) value of 7361 h^-1 at 323 K. The robust synergistic interactions between Pd NPs and Fe-N-C sites together with the small size effects of Pd NPs are responsible for the enhanced catalytic activity.

Keywords: Fe−N−C sites; catalysis; formic acid; hydrogen generation; palladium nanoparticles.

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Interfacing with Fe-N-C Sites Boosts the Formic Acid Dehydrogenation of Palladium Nanoparticles

Affiliations

Interfacing with Fe-N-C Sites Boosts the Formic Acid Dehydrogenation of Palladium Nanoparticles

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Abstract

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