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. 2022 Jan 7;87(1):524-530.
doi: 10.1021/acs.joc.1c02533. Epub 2021 Dec 27.

Stereoselective Palladium-Catalyzed Arylation of Exo-Glycals with Aryl Iodides

Jeffery Regier  1 , Supriya Ghanty  1 , Yuri Bolshan  1
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Stereoselective Palladium-Catalyzed Arylation of Exo-Glycals with Aryl Iodides

Jeffery Regier et al. J Org Chem. .

Abstract

A novel methodology for the arylation of exo-glycals has been developed. A range of exo-glycals underwent reactions with aryl iodides in the presence of a palladium catalyst. The transformation proceeded in a stereoselective manner to afford Z-isomers. The developed transformation demonstrated excellent functional group tolerance.

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