Improvement of heavy metal removal from urban runoff using modified pervious concrete

Abstract

Heavy metals are one of the major chemical pollutant groups in urban runoff. The application of porous concrete is a potential alternative to conventional runoff management systems with the ability to remove heavy metals. Hence, a thorough understanding of the heavy metal removal mechanisms and constraints of conventional porous concrete opens a path for the development of effective modifications. This review critically discusses the major contributors in ordinary porous concrete which supports heavy metal removal. The effects of initial concentration, contact time and competing ions on heavy metal removal using porous concrete are also discussed. Additionally, the effect of decalcification, atmospheric carbonation, acid influent on heavy metal removal is reviewed. The major drawback of porous concrete is the high pH (>8.5) of the effluent water, decalcification of the porous concrete and leaching of adsorbed pollutants. Overall, the addition of adsorbent materials to the porous concrete increases removal efficiencies (7% - 65% increase) without neutralizing the effluent pH. Meanwhile, the addition of Reduced Graphene Oxide is successful in reducing the leachability of the removed heavy metals. The addition of pozzolanic materials can lower the effluent pH while maintaining similar removal efficiencies to unmodified porous concrete. Therefore, developing a novel method of neutralizing the effluent pH must be prioritized in future studies. Additionally, the toxicity that can occur due to the abrasion of modified porous concrete requires study in future research. Further, advanced characterization methods should be used in future studies to understand the mechanisms of removal via the modified porous concrete materials.

Keywords: Concrete; Heavy metals; Stormwater; Treatment; Water pollution.