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. 2022 Mar 14;17(6):e202200093.
doi: 10.1002/asia.202200093. Epub 2022 Feb 21.

Heteroleptic Tripalladium(II) Cages

James A Findlay  1 , Komal M Patil  2 , Michael G Gardiner  1 , Hugo I MacDermott-Opeskin  1 , Megan L O'Mara  1 , Paul E Kruger  2 , Dan Preston  1
Affiliations

Heteroleptic Tripalladium(II) Cages

James A Findlay et al. Chem Asian J. .

Abstract

There is a concerted attempt to develop self-assembled metallo-cages of greater structural complexity, and heteroleptic PdII cages are emerging as prime candidates in these efforts. Most of these are dinuclear: few examples of higher nuclearity have been reported. We demonstrate here a robust method for the formation of tripalladium(II) cages from the 2 : 3 : 3 combination of a tritopic ligand, PdII , and a selection of ditopic ligands of the correct size and geometry.

Keywords: cages; heteroleptic; metallosupramolecular; palladium(II); self-assembly.

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References

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