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. 2022 Jul 19;51(28):10714-10720.
doi: 10.1039/d2dt00582d.

Bis(di- tert-butylindenyl)tetrelocenes

Liane Hildegard Staub  1 , Jessica Lambert  1 , Carsten Müller  1 , Bernd Morgenstern  1 , Michael Zimmer  1 , Joshua Warken  1 , Aylin Koldemir  2 , Theresa Block  2 , Rainer Pöttgen  2 , André Schäfer  1
Affiliations

Bis(di- tert-butylindenyl)tetrelocenes

Liane Hildegard Staub et al. Dalton Trans. .

Abstract

The synthesis and characterization of bis(di-tert-butylindenyl) germanium(II), tin(II) and lead(II) complexes are reported, which includes the first structurally authenticated example of a bis(indenyl)germanocene. The species were studied in detail in solution and in the solid, which includes single crystal X-ray diffraction and NMR spectroscopy, as well as Mössbauer spectroscopy of the tin compound.

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