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. 2022 May 6;87(9):6444-6453.
doi: 10.1021/acs.joc.2c00312. Epub 2022 Apr 25.

A Two-Step Approach to a Hexacyclic Lamellarin Core via 1,3-Dipolar Cycloaddition of Isoquinolinium Ylides to Nitrostilbenes

E A Silyanova  1 , A V Samet  1 , V V Semenov  1
Affiliations

A Two-Step Approach to a Hexacyclic Lamellarin Core via 1,3-Dipolar Cycloaddition of Isoquinolinium Ylides to Nitrostilbenes

E A Silyanova et al. J Org Chem. .

Abstract

The 1,3-dipolar cycloaddition reaction of isoquinolinium ylides to nitrostilbenes provides an approach to 1,2-diarylpyrrolo[2,1-a]isoquinolinium-3-carboxylates and then to a complete hexacyclic lamellarin core.

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