Microwave-Assisted Synthesis of Porous Composites MOF-Textile for the Protection against Chemical and Nuclear Hazards

Abstract

Since the emergence of chemical, biological, radiological, and nuclear risks, significant efforts have been made to create efficient personal protection equipment. Recently, metal-organic framework (MOF) materials have emerged as new promising candidates for the capture and degradation of various threats, like chemical warfare agents (CWAs) or radioactive species. Herein, we report a new synthesis method of MOF-textile composites by microwave irradiation, with direct anchoring of MOFs on textiles. The resistance of the composite has been tested using normed abrasion measurements, and non-stable samples were optimized. The protection capacity of the MOF-textile composite has been tested against dimethyl 4-nitrophenyl phosphate, a common CWA simulant, showing short degradation half-life (30 min). Radiological/nuclear protection has also been tested through uranium uptake (up to 15 mg g^-1 adsorbent) and the capture of Kr or Xe gas at 0.9 and 2.9 cm³/g, respectively.

Keywords: DMNP degradation; UiO-66; abrasion; microwave-assisted synthesis; radioactive species sorption; textiles.