Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2023 May 19;88(10):6523-6531.
doi: 10.1021/acs.joc.2c00712. Epub 2022 May 13.

Organophotoredox-Catalyzed Reductive Tetrafluoroalkylation of Alkenes

Vladislav S Kostromitin  1   2 , Vitalij V Levin  1 , Alexander D Dilman  1
Affiliations

Organophotoredox-Catalyzed Reductive Tetrafluoroalkylation of Alkenes

Vladislav S Kostromitin et al. J Org Chem. .

Abstract

A method for the hydroperfluoroalkylation of alkenes with 1,2-dibromotetrafluoroethane leading to tetrafluorinated bromides is described. The reaction is conveniently performed under blue light irradiation using an organic photocatalyst and ascorbic acid as a reducing agent. Primary products can be further functionalized via radical pathways affording various tetrafluorinated compounds.

PubMed Disclaimer

Similar articles

See all similar articles

Cited by

LinkOut - more resources