Novel co-polymerization of polypyrrole/polyaniline on ferrate modified biochar composites for the efficient adsorption of hexavalent chromium in water

Abstract

It is still a huge challenge to prepare cheap and effective composite materials for removing hexavalent chromium (Cr(VI)) in sewage treatment. In this study, a noval co-polymerization of polypyrrole/polyaniline on ferrate modified biochar (Ppy/PANI/FBC) was fabricated via ferrate-promoted pyrolysis and in-situ oxidative polymerization of pyrrole and aniline molecules to effectively remove Cr(VI) from polluted water. The Ppy/PANI/FBC quickly decreased Cr(VI) concentration from 38.92 to 3.92 mg/L within 400 min, with an efficient removal efficiency (89.92%), which was significantly higher than that of FBC (4.75%), Ppy/FBC (72.30%), and PANI/FBC (42.43%). These results are mainly caused by its conjugated connection and well-dispersion of Ppy and PANI on the surface of a carbon-based material. Meanwhile, the experimental results were in line with the pseudo-second-order kinetic and Freundlich models. The Ppy/PANI/FBC is featured by a high capacity of Cr(VI) adsorption (up to 203.71 mg/g). In addition, it could be adopted for efficiently removing Cr(VI) over a wide pH range (4-9) because of the positively charged nitrogen (-NH^.+- and = N⁺-). The sorption mechanisms of Cr(VI) were identified, including electrostatic interaction with surface protonated nitrogen (N⁺), ion exchange between the doped Cl^- ions and Cr(VI), chemical decrease of the Cr(VI) to Cr(III) by the iron valence cycle and efficient electron transfer of Ppy/PANI/FBC, as well as surface complexation by amine and oxygen-containing groups. More importantly, 97.98% Cr(VI) was efficiently removed in 20 min by coupling a photocatalytic reaction, also providing a novel idea for the practical use of adsorbents in wastewater treatment.

Keywords: Ferrate modified biochar; Hexavalent chromium; Mechanisms; Nitrogen-rich polymers; Water pollution.