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. 2022 Jul 12;51(27):10357-10360.
doi: 10.1039/d2dt00458e.

Luminescent early-late-hetero-tetranuclear group IV - Au(I) bisamidinate complexes

Cedric Uhlmann  1 , Thomas J Feuerstein  1 , Tim P Seifert  1 , André P Jung  1 , Michael T Gamer  1 , Ralf Köppe  1 , Sergei Lebedkin  2 , Manfred M Kappes  2   3 , Peter W Roesky  1
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Luminescent early-late-hetero-tetranuclear group IV - Au(I) bisamidinate complexes

Cedric Uhlmann et al. Dalton Trans. .

Abstract

The versatile metalloligand [{HCCC(NDipp)2}2Au2] (dipp = 2,6-diisopropylphenyl) was converted into early-late heterotetrametallic complexes [{ClCp2MCCC(NDipp)2}2Au2] (M = Ti, Zr). These compounds show photoluminescence with either remarkably different (Ti) or similar (Zr) features as compared to related solely coinage metal containing acetylide amidinate complexes.

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