Localized recharge processes in the NE Mekong Delta and implications for groundwater quality

Abstract

Understanding recharge in the Mekong Delta is critical for the delta's groundwater resources, and requires the investigation of recharge processes at the local scale. In this study of the north eastern area of the Mekong Delta, time-series of environmental tracer data (δ¹⁸O, δ²H, major ions and ³H) and markers of rural pollution (NH₄ and NO₃) were used to highlight localized recharge and impacts on groundwater quality. Results highlighted new hydrological insights into recharge processes, including that the Pleistocene aquifer receives recent recharge (< 60 years), predominantly during high rainfall months (> 100 mm/month). However, due to shallow clay layers there are significant spatial variations in these recharge processes, which were observed in the seasonal fluctuation of groundwater δ¹⁸O values in groundwater. Wet season δ¹⁸O changes ranged from below analytical uncertainty (≤ 0.10 ‰) to up to 0.56 ‰, and the calculated fraction of rainfall contribution to the aquifer is ≤5 % to 16 %. Rainfall recharge via the acrisol soils results in low groundwater EC (20-55 μS/cm), acidic groundwater (pH 3.6-5.6), and may also have resulted in the low groundwater NO₃ concentrations (≤ 5.3 mg NO₃/L) at many sites due to adsorption, therefore delaying not reducing NO₃ contamination. Site specific variations in nitrogen processes includes increased NO₃ (to 29.7 mg/L) from fertiliser transfers or nitrification, and increased NH₄ (to 1.4 mg/L) likely due to the recharge of irrigation waters. Unlike other recharge areas across the northern Mekong Delta, this north-eastern region provides a groundwater resource unaffected by arsenic contamination. Therefore, these results should inform on priority areas for protection from further contamination by rural anthropogenic activities.

Keywords: Acidity; Groundwater; Localized recharge; Nitrate; Stable isotopes; Tritium.