Review: Hydrothermal treatment of per- and polyfluoroalkyl substances (PFAS)

Abstract

PER: and polyfluoroalkyl substances (PFAS) are a concerning and unique class of environmentally persistent contaminants with biotoxic effects. Decades of PFAS discharge into water and soil resulted in PFAS bioaccumulation in plants, animals, and humans. PFAS are very stable, and their treatment has become a global environmental challenge. Significant efforts have been made to achieve efficient and complete PFAS mineralization using existing and emerging technologies. Hydrothermal treatments in subcritical and supercritical water have emerged as promising end-of-life PFAS destruction technologies, attracting the attention of scholars, industry, and key stakeholders. This paper reviews the state-of-the-art research on the behavior of PFAS, PFAS precursors, PFAS alternatives, and PFAS-containing waste in hydrothermal processes, including the destruction and defluorination efficiency, the proposed reaction mechanisms, and the environmental impact of these treatments. Scientific literature shows that >99% degradation and >60% defluorination of PFAS can be achieved through subcritical and supercritical water processing. The limitations of current research are evaluated, special considerations are given to the challenges of technology maturation and scale-up from laboratory studies to large-scale industrial application, and potential future technological developments are proposed.

Keywords: PFAS Degradation efficiency; Per- and polyfluoroalkyl substances; Reaction mechanism; Subcritical hydrothermal treatment; Supercritical water oxidation.