Functionalized magnetic nanostructured composites and hybrids for photocatalytic elimination of pharmaceuticals and personal care products

Abstract

Due to rapid urbanization and globalization, an enormous use of pharmaceuticals and personal care products (PPCPs) has resulted their excessive release in water bodies leading to several environmental issues. This release into the environment takes place via household sewage, hospital effluents, manufacturing units and landfill sites etc. The pharmaceuticals and personal care products (PPCPs) are recently listed as emerging contaminants having many adverse effects towards aquatic life, human beings, and the whole ecosystem. The alarming threats of PPCPs demand efficient methods to cope up their hazardous impacts. The conventional wastewater remediations are not specifically designed for the removal of PPCPs and hence, they require advanced technologies and materials for their elimination to ensure water safety. Among various methods employed so far, photocatalysis is considered to be one of the most cost effective and eco-friendly method but it requires a suitable candidate as a photocatalyst. Thanks to the magnetic nanocomposites which have improved the limitations (poor stability, agglomeration, and difficult separation, etc.) of classically used nanomaterials. Magnetic nanocomposites contain at least one component having magnetic properties making their separation easy from the aqueous media after the photodegradation phenomenon. These can be further functionalized with other materials to obtain maximum advantage as photocatalyst. Few examples of such functionalized nanocomposites are inorganic material based magnetic nanocomposites, carbon based magnetic nanocomposites, biomaterial based magnetic nanocomposites, metal-organic framework based magnetic nanocomposites and polymer based magnetic nanocomposites etc. This review covers the global environmental issue of water pollution especially with respect to the PPCPs, their occurrence in aqueous environment and toxic effects on living beings. A comprehensive discussion of the recently reported functionalized magnetic nanocomposites for the photocatalytic removal of PPCPs from water is the main aim of this review. The synthetic/morphological approaches of various functionalized magnetic composites and their mechanism of action are also elaborated. The possible research challenges in the field of magnetic nanocomposites and future research directions are discussed to apply magnetic nanocomposites for wastewater treatment in near future.

Keywords: Magnetic nanocomposites; Magnetic separation; Personal care products; Pharmaceuticals; Photocatalysis; Wastewater treatment.