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. 2022 Jul 19;78(Pt 8):818-820.
doi: 10.1107/S2056989022007228. eCollection 2022 Aug 1.

2-Amino-4-ferrocenyl-thia-zole

Bertin Anzaldo  1 , Pankaj Sharma  1 , Claudia P Villamizar  1 , Rene Gutierrez Perez  2 , Rubén A Toscano  1
Affiliations

2-Amino-4-ferrocenyl-thia-zole

Bertin Anzaldo et al. Acta Crystallogr E Crystallogr Commun. .

Abstract

The title compound, [Fe(C5H5)(C8H7N2S)], was synthesized by the direct reaction of acetyl-ferrocene, thio-urea and resublimed iodine. The structure shows one mol-ecule in the asymmetric unit. The amino-thia-zole ring makes an angle of 14.53 (13)° with the ferrocenyl ring to which it is attached. In the crystal, pairs of complex mol-ecules inter-act via inter-molecular N-H⋯N hydrogen bonds, forming a cyclic dimer which then inter-acts with other dimers through C-H⋯π inter-actions.

Keywords: amino­thia­zole; crystal structure; ferrocene; thia­zole.

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Figures

Figure 1
Figure 1
Structure of 2-amino-4-ferrocenyl­thia­zole. Displacement ellipsoids are drawn at the 30% probability level.
Figure 2
Figure 2
The packing of the title compound. The dotted lines indicate inter­molecular hydrogen bonds. All H atoms not involved in these inter­actions have been omitted for clarity.
See this image and copyright information in PMC

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