Hybrid Silver Nanowire-CMC Aerogels: From 1D Nanomaterials to 3D Electrically Conductive and Mechanically Resistant Lightweight Architectures

Abstract

The directed assembly of nanomaterials into 3D architectures is a powerful tool to produce macroscopic materials with tailored physical properties. We show in this article that such a process can be advantageously performed for the fabrication of lightweight electrically conductive materials. Silver nanowire aerogels (AgNWAs) with very low densities (down to ∼6 mg cm^-3) were ice-templated and freeze-dried, leading to 3D shaped cellular materials based on one-dimensional nanoscopic building blocks. Due to their intrinsic moderate mechanical resistance, the potential use of pure AgNWAs in real life applications appears rather limited. We demonstrate that the addition of carboxymethylcellulose (CMC) in a 1:1 weight ratio leads to the fabrication of hybrid aerogels with highly improved mechanical properties. The molecular weight of the CMC is shown to be a critical parameter to ensure a good dispersion of the AgNWs, and thus to reach excellent performances such as a very low resistivity (0.9 ± 0.2 Ω·cm at 99.2 vol % porosity). The combination of silver nanowires with CMC-700k results in a gain higher than 7100% of the Young's modulus, from 10.4 ± 0.9 kPa (at very low density, i.e., 12 mg cm^-3) for the AgNWAs to 740 ± 40 kPa for the AgNW:CMC aerogel. Electromechanical characterizations allowed us to quantify the piezoelectric properties of these hybrid aerogels. The very good elasticity and the piezoelectric behavior stability up to 100 cycles of compression under high (50%) deformation were revealed, which may be of interest for various applications such as pressure sensors.

Keywords: aerogel; cellulose; freeze-drying; ice-templating; nanowires; piezoresistivity; pressure sensor.