Synthesis and characterization of g-C3N4-CoFe2O4-ZnO magnetic nanocomposites for enhancing photocatalytic activity with visible light for degradation of penicillin G antibiotic

Abstract

Nowadays, antibiotic water pollution is an increasingly dangerous environmental threat. Thus, water treatment is essential for their reduction and removal. In recent decades, photocatalysts have attracted much attention due to their influential role in solving this issue. The photocatalytic process, which is one of the green processes and part of advanced oxidation processes, can be a good choice for treating contaminated water containing non-degradable organic matter. However, the design of high-performance photocatalysts under free sunlight can be challenging. In this study, g-C₃N₄-Ca, Mg codoped CoFe₂O₄-ZnO (gCN-CFO-ZnO) nanocomposite photocatalyst was applied in removing penicillin G (PENG) from drug effluents. Also, the effects of contaminant concentration, initial pH, irradiation time, and zinc oxide ratio in the nanocomposites were investigated. The hydrothermal method was carried out to prepare the appropriate composites. Then, the obtained products were characterized by powder X-Ray diffraction (PXRD), Fourier-transform infrared spectroscopy (FT-IR), Raman, field-emission scanning and transmission electron microscope (FE-SEM&TEM), energy dispersive X-Ray (EDX), diffuse reflectance spectroscopy (DRS), vibrating sample magnetometer (VSM) and Photoluminescence (PL) techniques. According to the findings, the degradation of PENG in an acidic environment occurred remarkably; under the same conditions, with decreasing pH from 9 to 5 in the gCN-CFO-ZnO (33.33%) nanocomposite, the degradation efficiency grew from 47% to 74%. Also, the degradation rate of PENG in gCN-CFO-ZnO (16.66%) and gCN-CFO-ZnO (50%) nanocomposites under optimal conditions (pH = 5, PENG the concentration of 10 ppm, and irradiation time of 120 min) was achieved 52% and 60%, respectively. Further, gCN-CFO-ZnO (33.33%) nanocomposite showed higher efficiency in PENG degradation compared to the other two nanocomposites.

Keywords: Antibiotic; G–C(3)N(4)–CoFe(2)O(4)–ZnO; Penicillin G; Photocatalytic activity; Visible light.