Recent Trends in Photocatalytic Enantioselective Reactions
- PMID: 36112295
- DOI: 10.1007/s41061-022-00402-9
Recent Trends in Photocatalytic Enantioselective Reactions
Abstract
Enantioselective synthesis through photocatalysis is one of the highly preferred approaches towards preparation of optically active compounds. This review elaborates and critically analyzes the different strategies of photocatalytic enantioselective reactions through H-bonding, transition metal catalysis, phase-transfer catalysis (PTC), chiral Lewis acid catalysis, N-heterocyclic carbene catalysis, and amine catalysis, and also explores ion pairs. In addition, it explains the different catalysis modes with multifunctional approaches for enantioselective photocatalytic reactions.
Keywords: Dual catalysis; Enantioselective reaction; Photocatalyst; Types of catalytic mode.
© 2022. The Author(s), under exclusive licence to Springer Nature Switzerland AG.
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References
-
- Noyori R (2002) Asymmetric catalysis: science and opportunities (Nobel lecture). Angew Chem Int Ed 41:2008–2022
-
- Blaser HU, Pugin B, Spindler F (2012) Asymmetric hydrogenation. Top Organomet Chem 42:65–102
-
- Sharpless KB (2002) Searching for new reactivity (Nobel Lecture). Angew Chem Int Ed 41:2024
-
- Krendlinger E, Heinrichs FL (2001) Performance enhancers. Polym Paint Colour J 190:22–24
-
- Yoon TP, Jacobsen EN (2003) Privileged chiral catalysts. Science 299:1691–1693 - PubMed