Possible realization of three-dimensional quantum spin liquid behavior in HoVO4

Abstract

The study of geometrically frustrated magnetic systems with unusual crystal field ground states offers a possibility of realizing the new aspects of physics of disordered systems. In this study, we report our results of structural, magnetic susceptibility, heat capacity measurements, along with density functional theory (DFT) calculations on HoVO₄; a compound in which the presence of a distorted kind of HoO₈polyhedral leads to multiple magnetic interaction paths. The observed broad maximum below 10 K in the temperature response of DC susceptibility curves implies the presence of short-range correlations. AC susceptibility rules out the possibility of any kind of spin freezing. Temperature dependent heat capacity measurement at zero field indicate towards the absence of long-range ordering, along with the presence of a broad maximum centered around 14 K. The residual heat capacity exhibits a characteristic power-law (T^α) behavior with the exponentαnearly equal to 2, which is analogous to that observed for other three-dimensional (3D) quantum spin liquid (QSL) systems. The DFT calculations signify the presence of dominant second and third nearest neighbor interactions, which in turn lead to magnetic frustration in our system. Our investigations suggest that HoVO₄can be a candidate for realizing a 3D QSL state.

Keywords: density functional theory; frustrated magnetism; quantum spin liquid.