doi: 10.1021/acs.joc.2c01827.
Epub 2022 Oct 6.
Eosin Y-Catalyzed Visible-Light-Induced Hydroperfluoroalkylation of Electron-Deficient Alkenes
Affiliations
- PMID: 36200531
- DOI: 10.1021/acs.joc.2c01827
Item in Clipboard
Eosin Y-Catalyzed Visible-Light-Induced Hydroperfluoroalkylation of Electron-Deficient Alkenes
J Org Chem.
.
Abstract
The eosin Y-catalyzed hydroperfluoroalkylation of electron-deficient alkenes is described herein. The reaction proceeded smoothly under visible light irradiation and selectively afforded a hydroperfluoroalkylated product. Various perfluoroalkyl bromides and electron-deficient olefins can be used in this reaction, and all chemicals required for this reaction are safe and readily available.
Similar articles
-
Metal-Free Visible Light Hydroperfluoroalkylation of Unactivated Alkenes Using Perfluoroalkyl Bromides.Org Lett. 2019 Jan 4;21(1):138-141. doi: 10.1021/acs.orglett.8b03596. Epub 2018 Dec 21. Org Lett. 2019. PMID: 30576147
-
Organophotoredox-Catalyzed Reductive Tetrafluoroalkylation of Alkenes.J Org Chem. 2023 May 19;88(10):6523-6531. doi: 10.1021/acs.joc.2c00712. Epub 2022 May 13. J Org Chem. 2023. PMID: 35561256
-
CuCl2 -Catalyzed α-Chloroketonation of Aromatic Alkenes via Visible-Light-Induced LMCT.Chem Asian J. 2023 Jan 3;18(1):e202200954. doi: 10.1002/asia.202200954. Epub 2022 Nov 25. Chem Asian J. 2023. PMID: 36378015
-
Visible-Light-Induced Carbo-2-pyridylation of Electron-Deficient Alkenes with Pyridinium Salts.Angew Chem Int Ed Engl. 2017 Aug 28;56(36):10877-10880. doi: 10.1002/anie.201704385. Epub 2017 Jul 28. Angew Chem Int Ed Engl. 2017. PMID: 28682453
-
From α-arylation of olefins to acylation with aldehydes: a journey in regiocontrol of the Heck reaction.Acc Chem Res. 2011 Aug 16;44(8):614-26. doi: 10.1021/ar200053d. Epub 2011 May 25. Acc Chem Res. 2011. PMID: 21612205 Review.
Cited by
-
A Comprehensive Review of Radical-Mediated Intramolecular Cyano-Group Migration.Molecules. 2025 Jul 14;30(14):2959. doi: 10.3390/molecules30142959. Molecules. 2025. PMID: 40733223 Free PMC article. Review.
-
CO2-DBU-Triggered Photoredox-Catalyzed Direct α-C-H Alkylation of Alcohols.Adv Sci (Weinh). 2025 Aug;12(31):e07490. doi: 10.1002/advs.202507490. Epub 2025 Jun 9. Adv Sci (Weinh). 2025. PMID: 40488345 Free PMC article.
-
Hydroxy- and Hydro-Perfluoroalkylation of Styrenes by Controlling the Quenching Cycle of Eosin Y.Molecules. 2023 Nov 14;28(22):7577. doi: 10.3390/molecules28227577. Molecules. 2023. PMID: 38005299 Free PMC article.
LinkOut - more resources
Full Text Sources
