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. 2022 Nov 4;87(21):14923-14929.
doi: 10.1021/acs.joc.2c01827. Epub 2022 Oct 6.

Eosin Y-Catalyzed Visible-Light-Induced Hydroperfluoroalkylation of Electron-Deficient Alkenes

Satsuki Shigenaga  1 , Haruko Shibata  1 , Koto Tagami  1 , Tadashi Kanbara  1 , Tomoko Yajima  1
Affiliations

Eosin Y-Catalyzed Visible-Light-Induced Hydroperfluoroalkylation of Electron-Deficient Alkenes

Satsuki Shigenaga et al. J Org Chem. .

Abstract

The eosin Y-catalyzed hydroperfluoroalkylation of electron-deficient alkenes is described herein. The reaction proceeded smoothly under visible light irradiation and selectively afforded a hydroperfluoroalkylated product. Various perfluoroalkyl bromides and electron-deficient olefins can be used in this reaction, and all chemicals required for this reaction are safe and readily available.

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