Degradation of organic pollutants from water by biochar-assisted advanced oxidation processes: Mechanisms and applications

Abstract

Biochar has shown large potential in environmental remediation because of its low cost, large specific surface area, porosity, and high conductivity. Biochar-assisted advanced oxidation processes (BC-AOPs) have recently attracted increasing attention to the remediation of organic pollutants from water. However, the effects of biochar properties on catalytic performance need to be further explored. There are still controversial and knowledge gaps in the reaction mechanisms of BC-AOPs, and regeneration methods of biochar catalysts are lacking. Therefore, it is necessary to systematically review the latest research progress of BC-AOPs in the treatment of organic pollutants in water. In this review, first of all, the effects of biochar properties on catalytic activity are summarized. The biochar properties can be optimized by changing the feedstocks, preparation conditions, and modification methods. Secondly, the catalytic active sites and degradation mechanisms are explored in different BC-AOPs. Different influencing factors on the degradation process are analyzed. Then, the applications of BC-AOPs in environmental remediation and regeneration methods of different biochar catalysts are summarized. Finally, the development prospects and challenges of biochar catalysts in environmental remediation are put forward, and some suggestions for future development are proposed.

Keywords: Advanced oxidation processes; Application; Biochar; Influencing factor; Mechanism; Regeneration.