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. 2020 Dec 4;5(Pt 12):x201576.
doi: 10.1107/S241431462001576X. eCollection 2020 Dec.

2-({[(2 S)-1-Hy-droxy-1,1,3-tri-phenyl-propan-2-yl]imino}-meth-yl)-4,6-bis-(4-methyl-phen-yl)phenol

Veronica L Show  1 , Emily Y Fok  1 , Adam R Johnson  1
Affiliations

2-({[(2 S)-1-Hy-droxy-1,1,3-tri-phenyl-propan-2-yl]imino}-meth-yl)-4,6-bis-(4-methyl-phen-yl)phenol

Veronica L Show et al. IUCrdata. .

Abstract

The title compound, C42H37NO2, crystallizes in the ortho-rhom-bic space group P212121 with one mol-ecule in the asymmetric unit. An intra-molecular hydrogen bond orients the phenol hydroxyl group toward the imine nitro-gen. The aliphatic alcohol is engaged in a weak intra-molecular hydrogen bond with the imine nitro-gen.

Keywords: Schiff base; chiral; crystal structure; tridentate ligand.

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Figures

Figure 1
Figure 1
The asymmetric unit of the title compound, showing the atom-numbering scheme. The displacement ellipsoids are shown at the 50% probability level. Hydrogen atoms apart from H1 and H2 have been omitted for clarity and intramolecular hydrogen bonds are shown as dashed lines. Figure generated using CrystalMaker (Palmer, 2020 ▸).
Figure 2
Figure 2
Synthesis of the title compound.
See this image and copyright information in PMC

References

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    1. Fok, E. Y., Show, V. L. & Johnson, A. R. (2020). Polyhedron. Submitted.
    1. Kang, Y.-F., Liu, L., Wang, R., Yan, W.-J. & Zhou, Y.-F. (2004). Tetrahedron Asymmetry, 15, 3155–3159.
    1. Liu, L., Kang, Y.-F., Wang, R., Zhou, Y.-F., Chen, C., Ni, M. & Gong, M.-Z. (2004). Tetrahedron Asymmetry, 15, 3757–3761.
    1. Palmer, D. (2020). CrystalMaker. CrystalMaker Software, Bicester, England.

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