Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2020 Jan 31;5(Pt 1):x200011.
doi: 10.1107/S2414314620000115. eCollection 2020 Jan.

2-[(5-Chloro-pyridin-2-yl-imino)-meth-yl]phenol

Krishnasamy Mamallan  1 , Sundaramoorthy Gomathi  1 , Krishnan Soundararajan  1 , Velusamy Sethuraman  1
Affiliations

2-[(5-Chloro-pyridin-2-yl-imino)-meth-yl]phenol

Krishnasamy Mamallan et al. IUCrdata. .

Abstract

In the title compound, C12H9ClN2O, the dihedral angle between the aromatic rings is 1.78 (4)° and an intra-molecular O-H⋯N hydrogen bond closes an S(6) ring. In the crystal, C-H⋯O and C-H⋯N hydrogen bonds connect the mol-ecules into [001] chains.

Keywords: crystal structure; hydrogen bonds.

PubMed Disclaimer

Figures

Figure 1
Figure 1
The mol­ecular structure of the title compound with displacement ellipsoids drawn at the 50% probability level. The O—H⋯N hydrogen bond is indicated by a dashed line.
Figure 2
Figure 2
Supra­molecular strands formed by weak C—H⋯N and C—H⋯O hydrogen bonds. Symmetry codes: (i) 1 − x, 1 − y, −z; (ii) formula image  − x, − formula image  + y, formula image  − z.
Figure 3
Figure 3
Left: Supra­molecular chain arising from Cl⋯Cl and C—Cl⋯π contacts. [Symmetry code: (iii) formula image  − x,- formula image  + y,1/2 − z; (iv) x,-1 + y, z]. Right: Honeycomb architecture formed by the weak non-covalent inter­actions.
See this image and copyright information in PMC

References

    1. Aboul-Fadl, T., Mohammed, F. A. & Hassan, E. A. (2003). Arch. Pharm. Res. 26, 778–784. - PubMed
    1. Bruker (2004). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Cason, C. J. (2004). POV-RAY for Windows. Persistence of Vision, Raytracer Pty Ltd, Victoria, Australia. URL: http://www.povray.org.
    1. Macrae, C. F., Bruno, I. J., Chisholm, J. A., Edgington, P. R., McCabe, P., Pidcock, E., Rodriguez-Monge, L., Taylor, R., van de Streek, J. & Wood, P. A. (2008). J. Appl. Cryst. 41, 466–470.
    1. Mannaert, E., Tytgat, J. & Daenens, P. (1997). J. Anal. Toxicol. 21, 208–212. - PubMed

LinkOut - more resources