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. 2022 May 17;7(Pt 5):x220489.
doi: 10.1107/S2414314622004898. eCollection 2022 May.

Bis-(3-methyl-1-propyl-1,3-di-hydro-1 H-imidazol-2-yl-idene)silver(I) chlor-ido(5,10,15,20-tetra-phenyl-porphin-ato)cadmate(II)

J P J Bruekers  1 , J A A W Elemans  1 , R J M Nolte  1 , P Tinnemans  1
Affiliations

Bis-(3-methyl-1-propyl-1,3-di-hydro-1 H-imidazol-2-yl-idene)silver(I) chlor-ido(5,10,15,20-tetra-phenyl-porphin-ato)cadmate(II)

J P J Bruekers et al. IUCrdata. .

Abstract

The structure of the title salt, [Ag(C7H12N2)2][CdCl(C44H28N4)], at 150 K has triclinic symmetry. One of the phenyl rings bonded to the porphyrin mol-ecule and the propyl groups of both yl-idene mol-ecules coordinating to silver are disordered over two positions.

Keywords: cadmium(II) porphyrin; crystal structure; silver(I)carbene.

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Figures

Figure 1
Figure 1
The structures of the mol­ecular entities in the title salt. Displacement ellipsoids are drawn at the 50% probability level. The minor-occupied sites of the disordered atoms have been omitted for clarity.
Figure 2
Figure 2
Two units of the stacked title salt, showing the offset stack alignment of the porphyrin planes relative to each other. H atoms and the minor-occupied sites of the disordered atoms have been omitted for clarity
See this image and copyright information in PMC

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