Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2021 Apr 13;6(Pt 4):x210379.
doi: 10.1107/S2414314621003795. eCollection 2021 Apr.

4-(2,3-Di-chloro-phen-yl)piperazin-1-ium picrate

Udhayasuriyan Sathya  1 , Jeyaraman Selvaraj Nirmal Ram  1 , Sundaramoorthy Gomathi  2 , Shyamaladevi Ramu  2 , Samson Jegan Jennifer  3 , Abdul Razak Ibrahim  4
Affiliations

4-(2,3-Di-chloro-phen-yl)piperazin-1-ium picrate

Udhayasuriyan Sathya et al. IUCrdata. .

Abstract

The title compound, C6H2N3O7 -·C10H13Cl2N2 +, crystallizes with one 1-(2,3-di-chloro-phen-yl)piperazine (DP) cation and one picrate (PA) anion in the asymmetric unit. In the crystal structure, the DP cation and PA anion are inter-connected via several N-H⋯O and C-H⋯O hydrogen bonds. The DP cation and PA anion are further connected through C-Cl⋯π [3.8201 (4), 3.7785 (4) Å] and N-O⋯π [3.7814 (4) Å] inter-actions. The DP cations are further inter-connected via a weak inter-molecular Cl⋯Cl [3.2613 (4) Å] halogen-halogen inter-action. The combination of these supra-molecular inter-actions leads to a herringbone like supra-molecular architecture.

Keywords: 1-(2,3-di­chloro­phen­yl)piperazinium picrate; crystal structure; supra­molecular inter­action.

PubMed Disclaimer

Figures

Figure 1
Figure 1
The title compound shown with 50% probability ellipsoids. The hydrogen bond is shown as a dashed line.
Figure 2
Figure 2
A view of the N—H⋯O and C—H⋯O hydrogen-bonded packing pattern of the title salt.
Figure 3
Figure 3
The three dimensional herring bone supra­molecular architecture viewed along the a and c axis.
Figure 4
Figure 4
A view of the C—Cl⋯ π and N—O⋯π inter­actions involving the phenyl rings of the cation and anion (at symmetry positions x, y, z and 1 − x, −y, 1 − z) and the weak inter­molecular Cl⋯Cl halogen–halogen bond.
Figure 5
Figure 5
Reaction scheme.
See this image and copyright information in PMC

References

    1. Bernstein, J., Davis, R. E., Shimoni, L. & Chang, N. L. (1995). Angew. Chem. Int. Ed. Engl. 34, 1555–1573.
    1. Braun, D. E., Gelbrich, T., Kahlenberg, V., Tessadri, R., Wieser, J. & Griesser, U. J. (2009). J. Pharm. Sci. 98, 2010–2026. - PubMed
    1. Bruker (2009). APEX2, SADABS and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Cason, C. J. (2004). POV-RAY for Windows. Persistence of Vision, Raytracer Pty. Ltd, Victoria, Australia. URL: http://www.povray. org.
    1. Frank, H. M., GuoJun, Z. & QiPeng, Y. (2007). Journal of Beijing University of Chemical Technology, 34, 425–427.

LinkOut - more resources