Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2020 Jul 28;5(Pt 7):x200980.
doi: 10.1107/S2414314620009803. eCollection 2020 Jul.

trans-Diamminebis(1,2-di-cyano-ethene-1,2-di-thiol-ato)platinum(IV)

Mahaa J Siddiqui  1 , Volodymyr V Nesterov  2 , Matthew T Steidle  1 , Bradley W Smucker  1
Affiliations

trans-Diamminebis(1,2-di-cyano-ethene-1,2-di-thiol-ato)platinum(IV)

Mahaa J Siddiqui et al. IUCrdata. .

Abstract

The title compound, [Pt(C4N2S2)2(NH3)2], represents an octa-hedral platinum(IV) complex with two trans-ammine and two mnt (mnt = 1,2-di-cyano-ethene-1,2-di-thiol-ato) ligands. The Pt-N and Pt-S distances are consistent with those in other platinum(IV) complexes. As a result of a slight canting of the coordination of the mnt ligand to the platinum(IV) atom, the nitrile nitro-gen atoms are positioned suitably to hydrogen-bond with adjacent ammines.

Keywords: crystal structure; di­thiol­ene; platinum(IV).

PubMed Disclaimer

Figures

Figure 1
Figure 1
Displacement ellipsoid plot 50% probability of all non-H atoms showing N—H hydrogen bonding between nitrile nitro­gen atoms and hydrogen atoms on adjacent ammines. Symmetry codes: (i) −x, y −  formula image , −z +  formula image ; (ii) x, −y +  formula image , z +  formula image .
See this image and copyright information in PMC

References

    1. Brawner, S. A., Lin, I. J. B., Kim, J.-H. & Everett, G. W. (1978). Inorg. Chem. 17, 1304–1308.
    1. Chandrasekaran, P., Greene, A. F., Lillich, K., Capone, S., Mague, J. T., DeBeer, S. & Donahue, J. P. (2014). Inorg. Chem. 53, 9192–9205. - PubMed
    1. Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K. & Puschmann, H. (2009). J. Appl. Cryst. 42, 339–341.
    1. Fanwick, P. E. & Huckaby, J. L. (1982). Inorg. Chem. 21, 3067–3071.
    1. Geiger, W. E., Barrière, F., LeSuer, R. J. & Trupia, S. (2001). Inorg. Chem. 40, 2472–2473. - PubMed

LinkOut - more resources