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. 2022 Jun 7;7(Pt 6):x220577.
doi: 10.1107/S2414314622005776. eCollection 2022 Jun.

2,6-Di-bromo-4-methyl-aniline

Ouarda Brihi  1 , Meriem Medjani  2 , Hassiba Bougueria  3 , Amel Djedouani  4 , Michelle Francois  5 , Solenne Fleutot  5 , Ali Boudjada  1
Affiliations

2,6-Di-bromo-4-methyl-aniline

Ouarda Brihi et al. IUCrdata. .

Abstract

In the title compound, C7H7Br2N, the C-C-C bond angles of the benzene ring are notably distorted and two short intamolecular N-H⋯Br contacts occur. In the crystal, the mol-ecules are linked by N-H⋯N hydrogen bonds to generate C(2) chains propagating in the [100] direction.

Keywords: N—H⋯N hydrogen bonds; aniline; crystal structure.

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Figures

Figure 1
Figure 1
The mol­ecular structure of the title compound showing displacement ellipsoids at the 50% probability level.
Figure 2
Figure 2
Views along the (a) b and (b) c axes of the crystal packing of the title compound with hydrogen bonds shown as dotted lines.
See this image and copyright information in PMC

References

    1. Brihi, O., Hamdouni, N., Boulcina, R., Medjani, M., Meinnel, J. & Boudjada, A. (2016). IUCrData, 1, x160351.
    1. Bruker (2016). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Altomare, A., Cascarano, G., Giacovazzo, C., Guagliardi, A., Burla, M. C., Polidori, G. & Camalli, M. (1994). J. Appl. Cryst. 27, 435.
    1. Farrugia, L. J. (2012). J. Appl. Cryst. 45, 849–854.
    1. Flack, H. D. (1983). Acta Cryst. A39, 876–881.

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