Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2021 Oct 13;6(Pt 10):x211016.
doi: 10.1107/S2414314621010166. eCollection 2021 Oct.

3',5'-Di-chloro- N, N-diphenyl-[1,1'-biphen-yl]-4-amine

Dinesh G Patel  1 , Jordan M Cox  2 , Branden M Bender  1 , Jason B Benedict  2
Affiliations

3',5'-Di-chloro- N, N-diphenyl-[1,1'-biphen-yl]-4-amine

Dinesh G Patel et al. IUCrdata. .

Abstract

The title tri-phenyl-amine derivative, C24H17Cl2N, featuring a 3,5-di-chloro-1,1'-biphenyl moiety has been synthesized and structurally characterized. The mol-ecular structure shows rotations of the phenyl rings in the range of 37-40° from the amine plane. In the crystal, the mol-ecules inter-act by van der Waals inter-actions.

Keywords: 3,5-di­chloro-1,1′-biphen­yl; crystal structure; tri­phenyl­amine derivative.

PubMed Disclaimer

Figures

Figure 1
Figure 1
The asymmetric unit of the title compound with atom numbering. Displacement ellipsoids are drawn at the 50% probability level.
Figure 2
Figure 2
Crystal packing of the title compound viewed along [010] illustrating head-to-tail dimer formation.
Figure 3
Figure 3
Crystal packing of the title compound viewed along [001]. Alternating layers are highlighted in blue and red.
Figure 4
Figure 4
Single sheet of the title compound viewed along [010].
Figure 5
Figure 5
Synthetic scheme for the preparation of the title compound.
See this image and copyright information in PMC

References

    1. Banno, M., Yamaguchi, T., Nagai, K., Kaiser, C., Hecht, S. & Yashima, E. (2012). J. Am. Chem. Soc. 134, 8718–8728. - PubMed
    1. Blanchard, P., Malacrida, C., Cabanetos, C., Roncali, J. & Ludwigs, S. (2019). Polym. Int. 68, 589–606.
    1. Bruker (2018). APEX3, SAINT, and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Dolomanov, O. V., Bourhis, L. J., Gildea, R. J., Howard, J. A. K. & Puschmann, H. (2009). J. Appl. Cryst. 42, 339–341.
    1. Hamilton, A. E., Buxton, A. M., Peeples, C. J. & Chalker, J. M. (2013). J. Chem. Educ. 90, 1509–1513.

LinkOut - more resources