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. 2022 Dec 6;7(Pt 12):x221151.
doi: 10.1107/S2414314622011518. eCollection 2022 Dec.

Diaceto-nitrile-(2,2'-bi-pyridine-κ2 N, N')palladium(II) bis-(tri-fluoro-methane-sulfonate)

Affiliations

Diaceto-nitrile-(2,2'-bi-pyridine-κ2 N, N')palladium(II) bis-(tri-fluoro-methane-sulfonate)

Rafael A Adrian et al. IUCrdata. .

Abstract

In the title complex, [Pd(C10H8N2)(CH3CN)2](CF3SO3)2 or [Pd(bipy)(CH3CN)2](CF3SO3)2, the palladium(II) ion is fourfold coordinated by two aceto-nitrile mol-ecules and a bidentate 2,2'-bi-pyridine ligand in a distorted square-planar geometry.

Keywords: 2,2′-bi­pyridine; 2,2′-dipyrid­yl; bipy; coordinated aceto­nitrile; coordination complex; crystal structure; palladium; square planar.

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Figures

Figure 1
Figure 1
The mol­ecular structure of the title compound with displacement ellipsoids drawn at the 50% probability level; H atoms are omitted for clarity. Symmetry code: (i) x, −y +  formula image , z.
Figure 2
Figure 2
Perspective view of the packing structure of the title complex; H atoms are omitted for clarity.

References

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