Non-Centrosymmetric Sr2IrO4 Obtained Under High Pressure

Abstract

Sr₂IrO₄ with strong spin-orbit coupling and Hubbard repulsion (U) hosts Mott insulating states. The similar crystal structure and magnetic and electronic properties, particularly the d-wave gap observed in Sr₂IrO₄ enhanced the analogies to the cuprate high-T_c superconductor, La₂CuO₄. The incomplete analogy was due to the lack of broken inversion symmetry phases observed in Sr₂IrO₄. Here, under high-pressure and high-temperature conditions, we report a noncentrosymmetric Sr₂IrO₄. The crystal structure and its noncentrosymmetric character were determined by single-crystal X-ray diffraction and high-resolution scanning transmission electron microscopy. The magnetic characterization confirms the Ir⁴⁺ with S = 1/2 at low temperature in Sr₂IrO₄ with magnetic ordering occurring at around 86 K, where a larger moment is observed than the ambient pressure Sr₂IrO₄. Moreover, the resistivity measurement shows three-dimensional Mott variable-range hopping (VRH) existed in the system. This noncentrosymmetric Sr₂IrO₄ phase appears to be a unique material that offers a further understanding of high-T_c superconductivity.