A synergistic consequence of catalyst dosage, pH solution and reactive species of Fe-doped CdAl2O4 nanoparticles on the degradation of toxic environmental pollutants

Abstract

Industrial wastewater treatment techniques are one of the biggest challenges of the scientific community that necessitate an increased consciousness to address water scarcity worldwide. Herein, an eco-friendly and cost-effective process was demonstrated to cope with tannery, textile and pharmaceutical dye wastes through the co-precipitation of highly reusable Fe-doped CdAl₂O₄ samples. The XRD studies exposed the space group R 3‾ with no secondary phase step being found for all samples. The outcomes of optical absorbance spectra demonstrate that Fe doping diminished the energy gap from 3.66 to 1.67 eV. HR-TEM images of existing spherical particles and some of the particles' rod-like structures with little agglomeration were found for Fe (0.075 M) doped CdAl₂O₄ nanoparticles. The PL emission outcomes show that Fe doping effectively prevented the charge carrier's recombination in CdAl₂O₄ during photocatalysis. All Fe-doped CdAl₂O₄ samples demonstrated higher photodegradation behaviors towards the effectual degradation of both dye solutions as compared to pure CdAl₂O₄ samples. Particularly, Fe (0.075 M)-doped CdAl₂O₄ samples exhibited improved photodegradation performance of 93 and 95% for both dye solutions. The amount of photodegradation was noticed to rely on dye pH, irradiation time, catalyst dosage, initial dye amount, and reactive species. The recyclability of the Fe (0.075 M) doped CdAl₂O₄ nanoparticles denotes that 78 and 82% of BB and BG were removed up to the 6th run of usage. The outcomes of trapping tests,^.OH^- and h⁺ radicals were the major Scavenging in the photodegradation reaction. COD studies affirmed the whole mineralization of BB and BG dye molecules. It is expected that our present examination could offer to improve various spinal oxide materials for the photodegradation activity of pharmaceutical contaminants and environmental issues and can also resolve energy storage applications.

Keywords: ESR; Fe-doped CdAl(2)O(4); Photodegradation; Photoluminescence; Scavenging species.