Crustacean polysaccharides for the geotechnical enhancement of organic silt: A clean and green alternative

Abstract

Biopolymer-based soil stabilization offers a clean alternative to conventional stabilizers like cement and lime. This study investigates the possibility of using shrimp-based chitin and chitosan for stabilizing low plastic silt with organic content by investigating their effect on pH, compaction, strength, hydraulic conductivity (HC) and consolidation characteristics. X-ray diffraction (XRD) spectrum shows that no new chemical compounds were formed in the soil on additive treatment; however, results of scanning electron microscope (SEM) analysis indicate the formation of biopolymer threads that bridge the voids in the soil matrix leading to a stiffer soil matrix, with increased strength and lower HC. Chitosan showed nearly 103 % strength enhancement after 28 d of curing with no degradation. However, chitin failed as a soil stabilizing additive as it showed degradation owing to fungal bloom after 14 d of curing. Chitosan can therefore be recommended as a non-polluting and sustainable soil additive.

Keywords: Chitin; Chitosan; Hydraulic conductivity; Organic silt; Strength; TGA.