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. 2023 May 5;88(9):5609-5621.
doi: 10.1021/acs.joc.3c00099. Epub 2023 Apr 26.

Blue LED-Mediated Synthesis of 3-Arylidene Oxindoles

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Blue LED-Mediated Synthesis of 3-Arylidene Oxindoles

Sengodagounder Muthusamy et al. J Org Chem. .

Abstract

Blue LED-promoted cross-coupling olefination of symmetrical and unsymmetrical 3-arylidene oxindoles has been described from diazoindolones and diphenylmethanethiones. Thermal olefin isomerization and stereoselective synthesis of 3-arylidene oxindoles were also demonstrated in good yield.

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