Supported Noble Metal Catalysts and Adsorbents with Soft Lewis Acid Functions

Haruno Murayama¹, Qi-An Huang¹, Eiji Yamamoto¹, Makoto Tokunaga¹, Tamao Ishida², Mitsutaka Okumura³, Tetsuo Honma⁴, Tadahiro Fujitani⁵, Atsuko Isogai⁶

Affiliations

¹ Department of Chemistry, Graduate School of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan.
² Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-osawa, Hachioji, Tokyo, 192-0397, Japan.
³ Department of Chemistry, Osaka University, Toyonaka, Osaka, 560-0043, Japan.
⁴ Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo, Hyogo, 679-5198, Japan.
⁵ National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki, 305-8565, Japan.
⁶ National Research Institute of Brewing (NRIB), Higashihiroshima, Hiroshima, 739-0046, Japan.

PMID: 37417711
DOI: 10.1002/tcr.202300148

Review

Supported Noble Metal Catalysts and Adsorbents with Soft Lewis Acid Functions

Haruno Murayama et al. Chem Rec. 2023 Nov.

. 2023 Nov;23(11):e202300148.

doi: 10.1002/tcr.202300148. Epub 2023 Jul 7.

Authors

Haruno Murayama¹, Qi-An Huang¹, Eiji Yamamoto¹, Makoto Tokunaga¹, Tamao Ishida², Mitsutaka Okumura³, Tetsuo Honma⁴, Tadahiro Fujitani⁵, Atsuko Isogai⁶

Affiliations

¹ Department of Chemistry, Graduate School of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan.
² Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-osawa, Hachioji, Tokyo, 192-0397, Japan.
³ Department of Chemistry, Osaka University, Toyonaka, Osaka, 560-0043, Japan.
⁴ Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo, Hyogo, 679-5198, Japan.
⁵ National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki, 305-8565, Japan.
⁶ National Research Institute of Brewing (NRIB), Higashihiroshima, Hiroshima, 739-0046, Japan.

PMID: 37417711
DOI: 10.1002/tcr.202300148

Abstract

Heterogeneous noble metal catalysts exhibit various functions. Although their redox functions have been extensively studied, we focused on their soft Lewis acid functions. Supported Au, Pt, and Pd catalysts electrophilically attack the π-electrons of soft bases such as alkynes, alkenes, and aromatic compounds to perform addition and substitution reactions. Hydroamination, intramolecular cyclization of alkynyl carboxylic acids, isomerization of allylic esters, vinyl exchange reactions, Wacker oxidation, and oxidative homocoupling of aromatics are introduced based on a discussion of the active species and reaction mechanisms. Furthermore, the adsorption of sulfur compounds, which are soft bases, onto the supported AuNPs is discussed. The adsorption and removal of 1,3-dimethyltrisulfane (DMTS), which is the compound responsible for the stale odor of "hine-ka" in alcoholic beverages, particularly Japanese sake, is described.

Keywords: adsorbents; noble metals; soft Lewis acids; soft Lewis bases; supported catalysts.

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References

1. None
1. R. H. Crabtreein, The Organometallic Chemistry of the Transition Metals, 7th Ed., Wiley, Hoboken, 2019;
1. B. Cornils, W. A. Herrmann, J.-H. Xu, H.-W. Zanthoff, in Catalysis from A to Z: A Concise Encyclopedia, 5th Ed., Wiley-VCH, Weinheim, 2019.
1. None
1. X. Liu, M. Haruta, M. Tokunaga, Chem. Lett. 2008, 37, 1290-1291;

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Supported Noble Metal Catalysts and Adsorbents with Soft Lewis Acid Functions

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Supported Noble Metal Catalysts and Adsorbents with Soft Lewis Acid Functions

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