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. 2023 Sep 15;25(36):6741-6745.
doi: 10.1021/acs.orglett.3c02601. Epub 2023 Aug 30.

Synthesis of 2-Indolyl C-Glycoside Neopetrosins A and C and Congeners via Ni-Catalyzed Photoreductive Cross-Coupling

Yan Xia  1 , Yingjie Wang  1 , Zhaolun Zhang  1 , Tayyab Gulzar  1 , Yuqi Lin  1 , Jing Wang  1 , Dapeng Zhu  2 , Biao Yu  1
Affiliations

Synthesis of 2-Indolyl C-Glycoside Neopetrosins A and C and Congeners via Ni-Catalyzed Photoreductive Cross-Coupling

Yan Xia et al. Org Lett. .

Abstract

The synthesis of neopetrosins A and C, two 2-indolyl C-α-d-mannopyranosides, and their congeners has been realized via a direct Ni/photoredox-catalyzed reductive coupling of 3-methoxycarbonyl-2-iodo-1H-indoles with pyranosyl bromides.

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