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. 2023 Sep 12;8(Pt 9):x230780.
doi: 10.1107/S2414314623007800. eCollection 2023 Sep.

(2,4-Di-chloro-benzyl-idene)[2-(1 H-indol-3-yl)eth-yl]amine

Affiliations

(2,4-Di-chloro-benzyl-idene)[2-(1 H-indol-3-yl)eth-yl]amine

Suganya Murugan et al. IUCrdata. .

Abstract

In the title compound, C17H14Cl2N2, the mol-ecule exists in an E configuration with respect to the C=N bond of the Schiff base fragment. The dihedral angle between the indole ring system and the benzene ring is 80.86 (12)°. In the crystal, mol-ecules are connected by N-H⋯N hydrogen bonds, generating a C(7) chain extending along the a-axis direction. No aromatic π-π stacking occurs but weak C-H⋯π inter-actions are observed.

Keywords: C—H⋯π inter­actions; crystal structure; hydrogen bonding.

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Figures

Figure 1
Figure 1
The mol­ecular structure of the title compound showing 50% displacement ellipsoids.
Figure 2
Figure 2
Partial packing diagram for the title compound showing the formation of [100] hydrogen-bonded chains.

References

    1. Agilent (2012). CrysAlis PRO and CrysAlis RED. Agilent Technologies Ltd, Yarnton, England.
    1. Arumugam, N., Almansour, A. I., Kumar, R. S., Yeswanthkumar, S., Padmanaban, R., Arun, Y., Kansız, S., Dege, N., Manohar, T. S. & Venketesh, S. (2021). J. Mol. Struct. 1225, 129165–129166.
    1. Brink, A., Kroon, R. E., Visser, H. G., van Rensburg, C. E. J. & Roodt, A. (2018). New J. Chem. 42, 5193–5203.
    1. Faizi, M. S. H., Dege, N., Malinkin, S. & Sliva, T. Y. (2017). Acta Cryst. E73, 1329–1332. - PMC - PubMed
    1. Groom, C. R., Bruno, I. J., Lightfoot, M. P. & Ward, S. C. (2016). Acta Cryst. B72, 171–179. - PMC - PubMed

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